There's no poison that I can see. The only "special" seems to be a chance to "curse" - with 100% for the head, 25% for the feet (and 10% when webbed). There's 2nd type of curse that has a 100% chance for the spit. I haven't really looked into what exactly each "curse" does.
Oh, and while I'm at it, the spider boss's resists:
physical=10
poison=50
magic=10
So Royal Snakes might be a poor choice to fight it, especially as it always retaliates.
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