The following, in bold type, are squadrons and the date for 100 octane fuel useage. Info came from mostly pilots combat reports.
The Aug and Sept dates don't necessarily mean this was the first use of 100 octane fuel but the first reference date I found on 100 octane fuel use.
Please add to the list if you have any other references of 100 octane use.
Hurricane Squadrons
No. 1 (Cawnpore) Squadron - May 1940
No. 3 Squadron - May 1940
No. 17 Squadron - May 1940
* No. 32 Squadron
No. 43 (China-British) Squadron - June 1940
* No. 46 (Uganda) Squadron
No. 56 (Punjab) Squadron - May 1940
No. 73 Squadron - May 1940
No. 79 (Madras Presidency) Squadron - May 1940
No. 85 Squadron - May 1940
No. 87 (United Provinces) Squadron - May 1940
* No. 111 Squadron
No. 145 Squadron July 1940
No. 151 Squadron - May 1940
* No. 213 (Ceylon) Squadron
* No. 229 Squadron
* No. 232 Squadron
* No. 238 Squadron
* No. 242 (Canadian) Squadron
* No. 245 (Northern Rhodesia) Squadron
No. 249 (Gold Coast) Squadron - 6 Sept 1940
* No. 253 (Hyderabad) Squadron
* No. 257 (Burma) Squadron
* No. 263 (Fellowship of the Bellows) Squadron
* No. 302 Polish Fighter Squadron
No. 303 Polish Fighter Squadron - 9 Sept 1940
* No. 310 Czechoslovak Squadron
* No. 312 Czechoslovak Squadron
* No. 401 Canadian Squadron
* No. 501 (County of Gloucester) Squadron
* No. 504 (City of Nottingham) Squadron
* No. 601 (County of London) Squadron
* No. 605 (County of Warwick) Squadron
* No. 607 (County of Durham) Squadron
* No. 615 (County of Surrey) Squadron
Spitfire Squadrons
No. 19 Squadron - e May 1940
No. 41 Squadron - June 1940
No. 54 Squadron - May 1940
No. 64 Squadron - 5 Aug 1940
No. 65 (East India) Squadron - 12 Aug 1940
No. 66 Squadron - 6 Sept 1940
* No. 72 (Basutoland) Squadron -
No. 74 Squadron - May 1940
* No. 92 (East India) Squadron
No. 152 (Hyderabad) Squadron - 4 Sept 1940
* No. 222 (Natal) Squadron
No. 234 (Madras Presidency) Squadron - 18 Aug 1940
* No. 266 (Rhodesia) Squadron
No. 602 (City of Glasgow) Squadron - pre BoB
No. 603 (City of Edinburgh) Squadron - 31 Aug 1940
No. 609 (West Riding) Squadron - pre BoB
No. 610 (County of Chester) Squadron - June 1940
No. 611 (West Lancashire) Squadron - June 1940
No. 616 (South Yorkshire) Squadron - 15 Aug 1940
Other aircraft
* No. 23 Squadron - Bristol Blenheim
* No. 25 Squadron - Bristol Blenheim and Bristol Beaufighter
* No. 29 Squadron - Bristol Blenheim and Bristol Beaufighter
* No. 141 Squadron - Boulton Paul Defiant
* No. 219 (Mysore) Squadron - Bristol Blenheim and Bristol Beaufighter
* No. 235 Squadron - Bristol Blenheim
* No. 236 Squadron - Bristol Blenheim
* No. 247 (China - British) Squadron - Gloster Gladiator
* No. 248 Squadron - Bristol Blenheim
* No. 264 (Madras Presidency) Squadron - Boulton Paul Defiant
* No. 600 (City of London) Squadron - Bristol Blenheim and Bristol Beaufighter
* No. 604 (County of Middlesex) Squadron - Bristol Blenheim and Bristol Beaufighter
* No. 804 Naval Air Squadron - Fairey Fulmar
* No. 808 Naval Air Squadron - Fairey Fulmar
Every Sector Station on the CloD map had 100 octane fuel.
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